Structure and composition of the atmosphere. Air pollution. Self-purification.
1. Structure and Composition of the Atmosphere
Definition:
- Atmosphere: The layer of gases surrounding the Earth, essential for life, climate regulation, and protection from harmful solar radiation.
Composition of Air (approx. % by volume):
- Nitrogen (N₂) – 78%
- Oxygen (O₂) – 21%
- Argon (Ar) – 0.93%
- Carbon dioxide (CO₂) – 0.03–0.04%
- Trace gases: Neon, Helium, CH₄, O₃, H₂, etc.
- Water vapor: 0–4% (depends on humidity and temperature)
- Suspended matter: dust, bacteria, spores
Functions of Air:
- Provides oxygen for life
- Facilitates cooling of the human body
- Transmits stimuli for hearing and smell
- Can carry disease agents
2. Air Pollution
Definition:
- The presence of harmful substances (gases, mixtures of gases, or particulate matter) in the atmosphere, in concentrations that:
- Interfere with human health, safety, or comfort
- Harm vegetation, animals, or environmental media
- Enter the food chain or drinking water
Sources of Air Pollution:
Natural Sources:
- Volcanic eruptions, dust storms, forest fires, pollen, sea salt, soil erosion
Anthropogenic (Human-Made) Sources:
- 1. Automobiles: Hydrocarbons, CO, lead, NOx, particulate matter; sunlight + UV Can convert some of these into photochemical oxidants (e.g., ozone).
- 2. Industries: Industrial activities, fuel combustion, and domestic burning of coal, wood, or oil release sulfur dioxide, nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen sulfide, hydrogen chloride, hydrogen fluoride, hydrocarbons, dust, fly ash, and polycyclic aromatic hydrocarbons.
- 3. Miscellaneous: This includes agricultural activities (like pesticides and fertilizers), nuclear energy programs, and natural contributions such as dust carried by wind or microbial activity (fungi and bacteria).
4. Dust and Particulates (Aerosols)
Definition: Particles in the air, either solid or liquid, such as dust, fumes, smoke, mists, or fogs.
Types of Dust:
- Organic: From plants, animals, or synthetic materials
- Inorganic:
- Metallic: Lead, cadmium, nickel
- Non-metallic: Silica-bearing or silica-free; can be crystalline or amorphous
Key Factors Affecting Exposure:
- 1. Type of dust (organic vs. inorganic)
- 2. Particle size:
- Respirable: <10 μm (can reach lower airways)
- Alveolar: <5 μm (can reach deep into lungs)
- 3. Concentration in the breathing zone
- 4. Duration of exposure
Health Effects:
- Respiratory: Fibrosis, chronic bronchitis, asthma, lung cancer
- Systemic (mainly metals): Liver, kidney, or CNS damage
- Infectious: Bacterial or fungal spores (e.g., anthrax, parasitic fungi)
- Irritation: Acid/alkali dust or chromates → nasal ulcers
- Radiation: Radioactive dust (e.g., radium) → tissue damage
5. Self-Purification of Air
Definition: Natural processes by which the atmosphere removes or reduces pollutants
Mechanisms:
- Dispersion:
- Wind and air currents spread pollutants, reducing their concentration.
- Deposition: